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张永明,男,1960年出生,1999年毕业于华东理工大学,获材料科学与工程专业博士学位,同年进入上海交通大学工作,现为上海交通大学教授,上海市领军人才,全国劳动模范,享受国务院政府特殊津贴专家,“泰山****”特聘专家。从事含氟聚合物和含氟功能膜的研发。主持并圆满完成国家863计划、支撑计划重大项目,实现了氯碱工业全氟离子膜的产业化,结束了中国没有全氟离子膜的历史,打破了制约我国氯碱工业安全运行和健康发展的瓶颈,是中国氯碱工业发展的里程碑。同时开展的研究包括燃料电池新能源汽车核心材料、催化分离膜材料、海水淡化膜材料、储能电池膜材料、特种润滑材料等。所著《含氟功能材料》被评为化工领域科技图书一等奖。
主要研究方向 特种功能高分子材料新能源汽车核心材料催化分离膜材料、储能电池膜材料光电功能材料与生物材料
主持项目 欧盟第七框架项目
“十五”863计划重大课题“全氟离子交换膜材料关键技术研究”
“十一五”国家支撑计划重大项目“全氟离子膜工程技术研究”
“十一五”863计划重点项目“新型制氢及高温质子交换膜燃料电池技术研发与应用示范”
“十二五”国家支撑计划重点项目“氯碱离子膜大规模应用研究”
欧盟第六框架项目
中加合作项目“新型燃料电池质子膜研究”
获奖情况 2007年山东省“泰山****”
2009年山东省技术发明一等奖(排名第一)
2010全国劳动模范
2010年享受国务院特殊津贴专家
2010年所著《含氟功能材料》获中国石化工业优秀出版物奖(图书奖)一等奖(排名第一)
2010年“全氟离子交换膜工程技术研究”入选“十一五”国家重大科技成就
2011年“全氟离子膜工程技术研究团队”获“十一五”国家科技计划执行优秀团队奖
2011年获中国石化联合会科技进步二等奖(排名第一)
2011年获国家技术发明二等奖(排名第一)
2012年获“何梁何利科学与技术进步奖”
2012年获“上海市领军人才”称号
2013年上海交通大学“凯原十佳教师” 主要学术兼职 国家分离膜标准化技术委员会委员
科技部国际合作评审专家
中国科技奖励评审专家
中国膜工业协会专家
中国氯碱协会专家
中国氟硅协会专家
中国无机盐协会专家
中国仪表功能膜材料协会专家
《膜科学与技术》编委
《氯碱工业》编委
Publication List 2013 69 Yuan, W. Z.; Tan, Y.; Gong, Y.; Lu, P.; Lam, J. W. Y.; Shen, X. Y.; Feng, C.; Sung, H. H-Y.; Lu, Y.; Williams, I. D.; Sun, J. Z.; Zhang, Y.; Tang, B. Z.“Synergy between Twisted Conformation and Effective Intermolecular Interactions: Strategy for Efficient Mechanochromic Luminogens with High Contrast”Advanced Materials2013, 26, 2837.68 Gong, Y.; Tan, Y.; Liu, J.; Lu, P.; Feng, C.; Yuan, W. Z.; Lu, Y.; Sun, J. Z.; He, G.; Zhang, Y.“Twisted D–pi–A solid emitters: efficient emission and high contrast mechanochromism”Chemical Communications2013, 49, 4009.67 Zhu, Y.; Pei, S.; Tang, J.; Li, H.; Wang, L.; Yuan, W. Z.; Zhang, Y.“Enhanced chemical durability of perfluorosulfonic acid membranes through incorporation of terephthalic acid as radical scavenger”Journal of Membrane Science2013, 432,66 Yang, L.; Tang, J.; Li, L.; Ai, F.; Chen, X.; Yuan, W. Z.; Zhang, Y.“Properties of precursor solution cast PFSI membranes with various ion exchange capacities and annealing temperatures”RSC Advances2013, 3, 7289.65 Tang, J.; Yuan, W.; Zhang, Z.; Li, H.; Zhang, Y.“Evidence for a crystallite-rich skin on perfluorosulfonate ionomer membranes”RSC Advances2013, 3, 8947.64 Wang, C.; Li, H.; Zhao, J.; Zhu, Y.; Yuan, W. Z.; Zhang, Y.“Graphene Nanoribbons as A Novel Support Material for High Performance Fuel Cell Electrocatalysts”International Journal of Hydrogen Energy2013, 38, 13230.63 Yang, L.; Li, H.; Ai, F.; Chen, X.; Tang, J.; Zhu, Y.; Wang, C.; Yuan, W. Z.; Zhang, Y.“A New Method to Prepare High Performance Perfluorinated Sulfonicacid Ionomer/Porous Expanded Polytetrafluoroethylene Composite Membranes Based on Perfluorinated Sulfonyl Fluoride Polymer Solution”Journal of Power Sources2013, 243, 392.62 Gong, YY.; Tan, YQ.; Mei, J.; Zhang, YR.; Yuan, WZ.; Zhang, YM.; Sun, JZ.; Tang, B. Z.“Room temperature phosphorescence from natural products: Crystallization matters”Science China Chemistry2013, 56, 1178.61 Gong, YY.; Tan, YQ.; Li, H.; Zhang, YR.; Yuan, WZ.; Zhang, YM.; Sun, JZ.; Tang, B. Z.“Crystallization-induced phosphorescence of benzils at room temperature”Science China Chemistry2013, 56, 1183.60 Lu, YW.; Tan, YQ.; Gong, YY.; Li, H.; Yuan, WZ.; Zhang, YM.; Tang, B. Z.“High efficiency D-A structured luminogen with aggregation-induced emission and mechanochromic characteristics”Chinese Science Bulletin2013, 58, 2719.
2012 59 Tang, J.; Yuan, W.; Wang, J.; Tang, J.; Li, H.; Zhang, Y.“Perfluorosulfonate ionomer membranes with improved through-plane proton conductivity fabricated under magnetic field”Journal of Membrane Science2012, 423–424, 267.58 Cai, Z.; Li, L.; Su, L.; Zhang, Y.“Supercritical carbon dioxide treated Nafion 212 commercial membranes for direct methanol fuel cells”Electrochemistry Communications2012, 14, 9.57 Cai, Z.; Liu, Y.; Zhao, J.; Li, L.; Zhang, Y.; Zhang, J.“Tris(trimethylsilyl) borate as electrolyte additive to improve performance of lithium-ion batteries”Journal of Power Sources2012, 202, 341.56 Yang, L.; Yuan, W.; Zhao, J.; Ai, F.; Chen, X.; Zhang, Y.“A Novel Approach to Prepare Uniaxially Aligned Nanofibers and Longitudinally Aligned Seamless Tubes Through Electrospinning”Macromolecular Materials and Engineering2012, 297, 604.55 Li, L.; Su, L.; Zhang, Y.“Enhanced performance of supercritical CO2 treated Nafion 212 membranes for direct methanol fuel cells”International Journal of Hydrogen Energy2012, 37, 4439.54 Cai, Z.; Liu, Y.; Liu, S.; Li, L.; Zhang, Y.“High performance of lithium-ion polymer battery based on non-aqueous lithiated perfluorinated sulfonic ion-exchange membranes”Energy Yuan, W. Z.; Zhao, J.; Yang, L.; Li, H.; Li, L.; Zhang, Y.“Thermal-mechanical stability of ethylene tetrafluoroethylene alternating copolymer, and modification thereof”Journal of Polymer Research2012, 19, 9820.52 Xu, A.; Yuan, W. Z.; Zhang, H.; Wang, L.; Li, H.; Zhang, Y.“Low-molecular-weight polytetrafluoroethylene bearing thermally stable perfluoroalkyl end-groups prepared in supercritical carbon dioxide”Polymer International2012, 61 , 901.51 Chen, X.; Yuan, W. Z.; Li, H.; Zhang, Y.“Rheological study on tetrafluoroethylene/hexafluoropropylene copolymer and its implication for processability”Journal of Applied Polymer Science2012, 125, 3361.50 Qin, S.; Li, H.; Yuan, W. Z.; Zhang, Y.“Fluorine-containing block copolymer particles with surface and internal hierarchical microphase separation structures”Soft Matter2012, 8, 2471.49 Qin, S.; Yuan, W. Z.; Li, H.; Zhang, Y.“Order–order phase transition and transformation in co-assembled particles from fluorinated FA/FB type diblock copolymers”Soft Matter2012, 8, 8405.48 Xu, A.; Li, H.; Yuan, W. Z.; Geng, B.; Zhang, S.; Zhang, H.; Wang, L.; Zhang, Y.“Radical homopolymerization of tetrafluoroethylene initiated by perfluorodiacyl peroxide in supercritical carbon dioxide: Reaction mechanism and initiation kinetics”European Polymer Journal2012, 48,1431.47 Yang, L.; Tang, J.; Li, L.; Chen, X.; Ai, F.; Yuan, W. Z.; Wang, L.; Zhang, Y.“High quality pristine perfluorosulfonated ionomer membranes prepared from perfluorinated sulfonyl fluoride solution”RSC Advances2012, 2, 5950.46 Chen, X.Y.; Yuan, W. Z.; Ai, F.; Li, H.; Li, L.; Wang, J.; Zhang, Y.“Melt rheological properties of ETFE: an attempt to illuminate the fluorine-substitution effect”Polymer Bulletin2012, 69, 375.45 Ai, F.; Wang, Q.; Yuan, W. Z.; Li, H.; Chen, X.; Yang, L.; Zhang, Y.; Pei, S.“Biocompatibility and anti-cracking performance of perfluorocarboxylic acid ionomer membranes for implantable biosensors”Journal of Materials Science2012, 47, 5181.44 Xu, A.; Yuan, W. Z.; Zhao, J.; Li, H.; Zhang, H.; Zhang, Y.“Copolymerizations of tetrafluoroethylene and perfluoropropylvinyl ether in supercritical carbon dioxide: Polymer synthesis, characterization, and thermal properties”Journal of Applied Polymer Science2012, 124, 1785.43 Zhu, H.; Tong, H.; Gong, Y.; Shao, S.; Deng, C.; Yuan, W. Z.; Zhang, Y.“Fluorene-and benzimidazole-based blue light-emitting copolymers: Synthesis, photophysical properties, and PLED applications”Journal of Polymer Science Part A: Polymer Chemistry2012, 50 , 2172.42 Qin, S.; Li, H.; Yuan, W. Z.; Zhang, Y.“Fabrication of polymeric honeycomb microporous films: breath figures strategy and stabilization of water droplets by fluorinated diblock copolymer micelles”Journal of Materials Science2012, 47, 6862.41 Ai, F.; Li, H.; Wang, Q.; Yuan, W. Z.; Chen, X.; Yang, L.; Zhao, J.; Zhang, Y.“Surface characteristics and blood compatibility of PVDF/PMMA membranes”Journal of Materials Science2012, 47, 5030.40 Chen, X. Y.; Zhang, Y. M.“Determining molecular weight scale and molecular weight distribution of ethylene-tetrafluoroethylene alternating copolymer via a rheological technique”Journal of Applied Polymer Science2012, 125, 2442.39 Yuan, W. Z.; Gong, Y.; Chen, S.; Shen, X. Y.; Lam, J. W.; Lu, P.; Lu, Y.; Wang, Z.; Hu, R.; Xie, N.“Efficient Solid Emitters with Aggregation-Induced Emission and Intramolecular Charge Transfer Characteristics: Molecular Design, Synthesis, Photophysical Behaviors, and OLED Application”Chemistry of Materials2012, 24, 1518.38 Yang, C.; Castelvetro, V.; Zhang, Y.; Hu, C.“Facile hydrophobic modification of hybrid poly (urethane-urea) methacrylate aqueous dispersions and films through blending with novel waterborne fluorinated acrylic copolymers”Colloid and Polymer Science2012, 290, 491.37 Ai, F.; Yuan, W. Z.; Wang, Q.; Li, H.; Zhang, Y.; Pei, S.“Enhancing the anti-cracking performance of perfluorosulfonic acid membranes for implantable biosensors through supercritical CO2 treatment”Journal of Materials Science2012, 47, 3602.
2011 36 Zhao, J.; Xu, A.; Yuan, W. Z.; Gao, J.; Tang, J.; Wang, L.; Ai, F.; Zhang, Y.“Evaluation of electrospun nanofiber formation of perfluorosulfonic acid and poly (N-vinylpyrrolidone) through solution rheology”Journal of Materials Science2011, 46, 7501.35 Peron, J.; Edwards, D.; Haldane, M.; Luo, X.; Zhang, Y.; Holdcroft, S.; Shi, Z.“Fuel cell catalyst layers containing short-side-chain perfluorosulfonic acid ionomers”Journal of Power Sources2011, 196, 179.34 Yang, C.; Castelvetro, V.; Scalarone, D.; Bianchi, S.; Zhang, Y.“Three different β-cyclodextrins direct the emulsion copolymerization of a highly fluorinated methacrylate toward distinctive nanostructured particle morphologies’’Journal of Polymer Science Part A: Polymer Chemistry2011, 49, 4518.33 Zhao, J.; Yuan, W. Z.; Xu, A.; Ai, F.; Lu, Y.; Zhang, Y.“Perfluorinated sulfonic acid ionomer/poly (N-vinylpyrrolidone) nanofiber membranes: Electrospinning fabrication, water stability, and metal ion removal applications”Reactive and Functional Polymers2011, 71, 1102.32 Luo, X.; Holdcroft, S.; Mani, A.; Zhang, Y.; Shi, Z.“Water, proton, and oxygen transport in high IEC, short side chain PFSA ionomer membranes: consequences of a frustrated network”Physical Chemistry Chemical Physics2011, 13, 18055.31 Xu, A.; Zhao, J.; Yuan, W. Z.; Li, H.; Zhang, H.; Wang, L.; Zhang, Y.“Tetrafluoroethylene Copolymers with Sulfonyl Fluoride Pendants: Syntheses in Supercritical Carbon Dioxide, Polymerization Behaviors, and Properties”Macromolecular Chemistry and Physics2011, 212, 1497.30 Qin, S.; Li, H.; Yuan, W.; Zhang, Y.“Hierarchical self-assembly of fluorine-containing diblock copolymer: From onion-like nanospheres to superstructured microspheres”Polymer2011, 52, 1191.29 Yuan, W. Z.; Chen, S.; Lam, J. W.; Deng, C.; Lu, P.; Sung, H. H.; Williams, I. D.; Kwok, H. S.; Zhang, Y.; Tang, B. Z.“Towards high efficiency solid emitters with aggregation-induced emission and electron-transport characteristics”Chemical Communications2011, 47, 11216.
2010 28 Li, L.; Shang, F.; Wang, L.; Pei, S.; Zhang, Y.“Transport properties of PFSA membranes with various ion exchange capacities for direct methanol fuel cell application”Energy Pei, S. P.; Li, H.; Ai, F.; Chen, H.; Li, K. Y.; Wang, Q.; Zhang, Y. M.“Study on an antifouling and blood compatible poly (ethylene–vinyl acetate) material with fluorinated surface structure”Journal of Materials Science2010, 45, 2788.26 Pei, S.; Qu, S.; Zhang, Y.“Direct Electrochemistry and Electrocatalysis of Hemoglobin at Mesoporous Carbon Modified Electrode”Sensors2010, 10, 1279.
2009 25 Zhao, H.; Yang, J.; Li, L.; Li, H.; Wang, J.; Zhang, Y.“Effect of over-oxidation treatment of Pt–Co/polypyrrole-carbon nanotube catalysts on methanol oxidation”International Journal of Hydrogen Energy2009, 34, 3908.24 Su, L.; Li, L.; Li, H.; Zhang, Y.; Yu, W.; Zhou, C.“Perfluorosulfonic acid membranes treated by supercritical carbon dioxide method for direct methanol fuel cell application”Journal of Membrane Science2009, 335, 118.23 Li, W.; Li, H.; Zhang, Y. M.“Preparation and investigation of PVDF/PMMA/TiO2 composite film”Journal of Materials Science2009, 44, 2977.22 Su, L.; Li, L.; Li, H.; Tang, J.; Zhang, Y.; Yu, W.; Zhou, C.“Preparation of polysiloxane modified perfluorosulfonic acid composite membranes assisted by supercritical carbon dioxide for direct methanol fuel cell”Journal of Power Sources2009, 194, 220.21 Su, L.; Pei, S.; Li, L.; Li, H.; Zhang, Y.; Yu, W.; Zhou, C.“Preparation of polysiloxane/perfluorosulfonic acid nanocomposite membranes in supercritical carbon dioxide system for direct methanol fuel cell”International Journal of Hydrogen Energy2009, 34, 6892.20 Shang, F.; Li, L.; Zhang, Y.; Li, H.“PWA/silica/PFSA composite membrane for direct methanol fuel cells”Journal of Materials Science2009, 44, 4383.19 Chen, H.; Li, H.; Pei, S.; Wen, X.; Zhang, Y.“Synthesis and characterization of fluoropoly (amide–sulfonamide) s via polycondensation”Polymer2009, 50, 4317.18 Chen, H.; Huang, Z.; Li, H.; Zhang, Y.; Liu, Y.“Synthesis of pure (Co) polymers via supported cobalt (II)-catalyzed controlled/“living” radical polymerization”Polymer Bulletin2009, 62, 151.17 Han, L.; Zhang, Y.; Li, H.; Li, L.“The synthesis and surface activity of perfluoro-2, 5-dimethyl-3,6-dioxanonanoic acid ester fluorocarbon surfactants’’Colloids and Surfaces A: Physicochemical and Engineering Aspects2009, 334, 176.
2008 16 Luan, Y.; Zhang, Y.; Zhang, H.; Li, L.; Li, H.; Liu, Y.“Annealing effect of perfluorosulfonated ionomer membranes on proton conductivity and methanol permeability”Journal of Applied Polymer Science2008, 107, 396.15 Huang, Z. X.; Zhang, Y. M.; Li, H.; Liu, Y. G.“Controlled/“living” radical polymerization of methyl methacrylate catalyzed by cobalt acetate”Macromolecular Chemistry and Physics2008, 209, 825.14 Luan, Y.; Zhang, H.; Zhang, Y.; Li, L.; Li, H.; Liu, Y.“Study on structural evolution of perfluorosulfonic ionomer from concentrated DMF-based solution to membranes”Journal of Membrane Science2008, 319, 91.13 Huang, Z. X.; Zhang, Y. M.; Li, H.; Luan, Y. H.; Liu, Y. G.“Atom transfer radical polymerization of methyl methacrylate catalyzed by ion exchange resin immobilized Co (II) hybrid catalyst”Journal of Polymer Science Part A: Polymer Chemistry2008, 46 , 1416.12 Li, L.; Zhang, Y. “Chemical modification of Nafion membrane with 3,4-ethylenedioxythiophene for direct methanol fuel cell application”Journal of Power Sources2008, 175, 256.11 Zhao, H.; Li, L.; Yang, J.; Zhang, Y.“Co@ Pt–Ru core-shell nanoparticles supported on multiwalled carbon nanotube for methanol oxidation”Electrochemistry Communications2008, 10, 1527.10 Zhao, H.; Li, L.; Yang, J.; Zhang, Y.“Nanostructured polypyrrole/carbon composite as Pt catalyst support for fuel cell applications”Journal of Power Sources2008, 184, 375.9 Luan, Y.; Zhang, Y.; Li, L.; Zhang, H.; Zhang, Q.; Huang, Z.; Liu, Y.“Perfluorosulfonic ionomer solution in N, N-dimethylformamide”Journal of Applied Polymer Science2008, 107, 2892.8 Zhao, H.; Li, L.; Yang, J.; Zhang, Y.; Li, H.“Synthesis and characterization of bimetallic Pt–Fe/polypyrrole–carbon catalyst as DMFC anode catalyst”Electrochemistry Communications2008, 10, 876.
2007 7 Huang, Z.; Zhang, Y.; Li, H.; Liu, Y.“A novel immobilized cobalt (II)/copper (II) bimetallic catalyst for atom transfer radical polymerization (ATRP) of methyl methacrylate”Applied Catalysis A: General2007, 332, 192.6 Li, L.; Zhang, Y.; Drillet, J. F.; Dittmeyer, R.; Jüttner, K.M.“Preparation and characterization of Pt direct deposition on polypyrrole modified Nafion composite membranes for direct methanol fuel cell applications”Chemical Engineering Journal2007, 133, 113.
2006 5 Li, H.; Zhang, Y. M.; Zhang, H.; Xue, M. Z.; Liu, Y. G.“Novel, well-defined polystyrene with a fluorine cluster end-capped group: Synthesis, characterization, and surface properties”Journal of Polymer Science Part A: Polymer Chemistry2006, 44, 3853.4 Huang, Z.; Zhang, Y.; Zhao, C.; Qin, J.; Li, H.; Xue, M.; Liu, Y.“Direct gas-phase epoxidation of hexafluoropropylene with molecular oxygen using Ag catalyst”Applied Catalysis A: General2006, 303, 18.
2005 3 Dou, H. Y.; Ni, H.-B.; Zhao, C.-X.; Zhang, Y. M.“EPR studies on H-abstraction from methylbenzenes by “magic blue” reagent”Journal of Fluorine Chemistry2005, 126, 1130.2 Li, Z. H.; Zhang, Y. M.; Xue, M. Z.; Zhou, L.; Liu, Y. G.“Atom transfer radical polymerization of methyl methacrylate catalyzed by cobalt catalyst system”Journal of Polymer Science Part A: Polymer Chemistry2005, 43, 5207.1 Li, Z.; Li, H.; Zhang, Y.; Xue, M.; Zhou, L.; Liu, Y.“A hybrid supported nickel catalyst for the controlled radical polymerization of methyl methacrylate”Applied Catalysis A: General2005, 292, 61.
著作 : 1生物高分子第2卷类聚异戊二烯/[日]古山种俊(Koyama, T.), [德] A.斯泰阴比歇尔(Steinbüchel, A.)主编;刘燕刚,薛敏钊,张永明主译.北京:化学工业出版社(现代生物技术与医药科技出版中心) 2004, 8.2含氟功能材料.张永明,李虹,张恒.北京:化学工业出版社2008.
3 PEM Fuel Cell Failure and Mode Analysis. Wang, H.; Li, H.; Yuan, X.-Z. Eds; Chapter 4, Luan, Y.; Zhang, Y. Membrane Degradation, Boca Raton: CRC Press, Taylor & Francis Group, 2011, December
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E-mail : ymzhang@sjtu.edu.cn
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